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As conventional electronic materials approach their physical limits, the application of ultrafast optical fields to access transient states of matter cap- tures imagination. The inversion symmetry governs the optical parity selection rule, differentiating between accessible and inaccessible states of matter. To circumvent parity-forbidden transitions, the common practice is to break the inversion symmetry by material design or external fields. Here we report how the application of femtosecond ultraviolet pulses can energize a parity-forbidden dark exciton state in black phosphorus while maintaining its intrinsic material symmetry. Unlike its conventional bandgap absorption in visible-to-infrared, femtosecond ultraviolet excitation turns on efficient Coulomb scattering, promoting carrier multiplication and electronic heating to ~3000 K, and consequently populating its parity-forbidden states. Interfero- metric time- and angle-resolved two-photon photoemission spectroscopy reveals dark exciton dynamics of black phosphorus on ~100 fs time scale and its anisotropic wavefunctions in energy-momentum space, illuminating its potential applications in optoelectronics and photochemistry under ultraviolet optical excitation. 

Abstract Modeling evaporationEfrom inland water bodies is challenging largely due to the uncertainties of input data, particularly surface water temperature that plays a key role in the available energy, i.e., net radiationR_nminus rate of water heat storage changeG. The equilibrium temperature approach (ETA) for estimating water surface temperature offers an alternative method to calculateR_nandGusing standard meteorological data. This study evaluates the global lakeEestimates from the widely used Penman model (PM) coupled with the ETA (PM-ETA) against field observations and model simulations from the Lake, Ice, Snow, and Sediment Simulator (LISSS). Our analysis reveals that the PM-ETA tends to overestimateEby approximately 36% and 24% compared to observations and the LISSS simulations, respectively, despite being driven by the same input data. The biases of the PM-ETAEare more pronounced in the cold and polar regions with distinct seasonality ofR_nandG. Furthermore, theEtrends from the PM-ETA deviate from the LISSS simulations over the period of 2001–16 due to the bias trends in the available energy. By incorporating the LISSS-simulatedR_nandGinto the PM, the bias inEis reduced to less than ±5% compared to the LISSS results. This study highlights the need to improve the available energy input of the PM to improve the estimates of global lakeEfor better water resource management and planning. Significance StatementThis study addresses a crucial challenge in modeling evaporationEfrom inland water bodies—uncertainties in surface water temperature and available energy inputs, particularly net radiationR_nand rate of heat storage changeG. By evaluating the widely used Penman model (PM) coupled with the equilibrium temperature approach (ETA), we reveal a tendency for the PM-ETA to overestimateEglobally, with the largest biases observed in cold and polar regions. Incorporating higher-qualityR_nandGestimates from the Lake, Ice, Snow, and Sediment Simulator (LISSS) significantly reduces these biases. These findings highlight the importance of alternative higher-quality data products for available energy inputs for improvingEestimates by the PM.